邢唷> jli欹g 鳵pbjbjVV2r<r< DD8TJln8l""""VVV7777777$b:=:7iVVVVV7""4(8555V""75V755O6w6"@苎e3zl/g67>80n8o6N=1?w6w6&N=b?$6VV5VVVVV772VVVn8VVVV?VVVVVVVVVD, p:  INCLUDEPICTURE "http://www.jnu.edu.cn/images/logo.gif" \* MERGEFORMATINET  2019t^踒6e;e麐Ux隭f[MOxvzueQf[諎諎槝 ******************************************************************************************** f[褃0NN T饄擽(uSf[ xvz筫T 諎褃顅 T饄831nfSf[ u鑜a@b gT{Hh臺{槞Q(WT{槝竳wS N 橯(W,g諎槝 NN媉 N賬R0 N0 愰b槝 ( 愰bN*NcknxT{Hh 蟢\槝2R 25槝qQ 50R) 1. 術NCQ1_x慔B剉Ka=1.010-9 vQSm:N0.1molL-1剉4l秐瞞剉pH0 NR豐S-N Nq_蚑s^a埗r`剉/f( ) A. GS貧)n B. 燫'YN2婼汻 C. 鯺曂S擽鰁魰 D. 恊QO2 9. (uKMnO4鬾歔Fe2+KNMR 燫eQ郠鬾MnSO4剉\O(u/f( ) A. 琍SBR B. 駤黐蚐擽BR C. 'lSBR D. MTBR諎褃顅nfSf[ qQ4u ,{1u 10. 蚐擽peI{嶯( ) A. 蚐擽筫 z_-NTir(崱嬒憄eKN孴 B. 悋s筫 z_-N蚐擽irSmy槃vcpeKN孴 C. 蚐擽RP[pe D. CQ蚐擽筫 z_-NTubir蠎peKN孴 11. 8^M6RFeSO4秐瞞鰁 燫eQ\蠎翑墧 vQ烻郪N NR蚐擽-N剉闠N*N鄀sQ( ) A.O2(aq)+4H+(aq)+4e EMBED Equation.DSMT4 2H2O(l) B. Fe3+(aq)+e EMBED Equation.DSMT4 Fe2+(aq) C. Fe(s)+2Fe3+(aq) EMBED Equation.DSMT4 3 Fe2+(aq) D. Fe3+(aq)+3e EMBED Equation.DSMT4 Fe(s) 12. 騗鍂298.15 K鰁 (Fe3+/Fe2+)=0.771 V (Hg2+/Hg)= 0.851 V R(Wh芉秗` N蚐擽 Hg 2Fe3+ EMBED Equation.DSMT4 Hg2++2Fe2+ ( ) A. ckT陙裇蹚L B. T陙裇蹚L C. N齹蹚L D. Nnx歔 13. 5u乬蚐擽Cu2++2e EMBED Equation.DSMT4 Cu剉:N0.347 V R5u乬蚐擽2Cu EMBED Equation.DSMT4 2Cu2++4e剉 D F L N V ^ b n p r ~ B H J j 疳郧俯俯俯笧暈墌瀝瀝瀋Pc瀋Pc%h荌h B*CJaJmHph3fsHh荌h CJaJmHsHh荌h CJH*aJhhCJaJh荌h CJH*aJh瞏TCJaJo(h荌h CJaJh荌hidnB*CJaJphh荌hJLNPTVXZ\^fhjlvxz|燧渭瑴渭瑴渭瑴渭瑴渭瑴渭瑴屛棘|渭瑴螌渭瑴渭瑴渭h荌h荌CJH*aJmHsHh荌h CJH*aJmHsHh荌h CJH*aJmHsHh荌h CJH*PJ]乤J"h荌h 6丆J]乤JmHsHh荌h CJaJmHsHh郖h+@CJaJmHsH%h郖h+@B*CJaJmHph3fsH0   "*:>@HPT\b镟尉镟长懁{f戉む赤赤长啶喑啶喑]赤h瞏TCJaJo()j$h荌h荌CJEHUaJmHsH+j彈卂 h荌h荌CJUVaJmHsH%jh荌h荌CJUaJmHsHh荌h荌CJaJmHsHh荌h CJaJh荌h CJH*PJ]乤J"h荌h 6丆J]乤JmHsHh荌h CJaJmHsHh荌h CJH*aJmHsH!bdhj(*燧逸戚逸份份逸逸л份л敺~i斴лU&jh荌he\B*EHUaJph)j'h荌h荌CJEHUaJmHsH+j煑卂 h荌h荌CJUVaJmHsH%jh荌h荌CJUaJmHsHh荌h CJH*aJmHsHh荌h荌CJaJmHsHh瞏TCJaJmHsHh荌h CJaJh荌h CJaJmHsH%h荌h B*CJaJmHph3fsHj N>d  F$Ifgde\ $$1$Ifa$gd} $Ifgd} $Ifgd}$ F$1$Ifa$gd $Ifgd  F$Ifgd *NPRTVlptvxz煺镰湇}峳峛峳K7璻&j-h荌h荌B*EHUaJph,j躄卂 h荌he\B*EHUVaJphh荌h CJH*aJmHsHh荌h CJaJh荌h CJH*aJmHsHh荌h CJaJmHsH h荌h 0JCJaJmHsH&jh荌he\B*EHUaJph&j.*h荌h荌B*EHUaJph,j釋卂 h荌he\B*EHUVaJph%h荌he\B*EHaJmHphsH&*HNVXbdjl燧洼洼洼土戳戳|g×S@%h荌h}B*EHaJmHphsH&jh荌h}B*EHUaJph)j0h荌h}CJEHUaJmHsH+j煑卂 h荌h}CJUVaJmHsHh荌h}CJaJmHsH%jh荌h}CJUaJmHsHh}CJH*aJmHsHh}CJaJmHsHh荌h CJH*aJmHsHh荌h CJaJmHsH%h荌h B*CJaJmHph3fsH"&*,.2BFRVZ^`bdfj檎恋瑹彽skks礬Mh荌h CJaJmHsHh荌h CJaJmHsHh}CJaJh}CJH*aJmHsHh}h}CJaJmHsHh}B*CJaJmHph3fsHh}CJaJmHo(sHh}CJaJo(h}CJaJmHsH&jh荌h}B*EHUaJph&j3h荌h}B*EHUaJph,j釋卂 h荌h}B*EHUVaJphjltvz~   "Z蹑瞩嫫蹑蹑瞩筏窋孵墊obSDoh荌hB*CJaJphh荌hBh荌h荌EHOJQJUaJmHsH/j槄_ h荌h荌OJQJUVaJmHsH)jh荌h荌OJQJUaJmHsHhKF=OJQJaJo( h荌hOJQJaJmHsHh荌h6H*OJQJaJh荌h6OJQJaJ h荌h荌OJQJaJmHsH h荌h6OJQJaJmHsH#h荌h6H*OJQJaJmHsH&*02`bdflnp|~镖锷急ū湐垟yh埍UG<睌h荌h荌CJaJh荌h6CJH*PJaJ$h荌h66丅*CJKHaJph!j闐h荌h荌CJEHUaJjF槄_ h荌CJUVaJjh荌CJUaJh荌CJaJh荌h6CJH*aJh&CJaJo(h荌h6CJaJh荌h6OJQJaJ h荌h6OJQJaJmHsH)h荌h6B*OJQJaJmHph3fsH h荌h6OJQJaJmHsH$\Jr4x2l F$Ifgd6 $Ifgd6剝剗$IfWD邶^剝`剗鹓d6 F劋$IfWD`劋gd6勔.$IfWD^勔`.gd6 F$Ifgd6*,~ 靥恋俩浟寉屃盗盗盗盗盗寉屃g羐羐#h荌h6CJOJQJ^JaJo(%h荌h6B*CJaJmHph3fsHh荌h6CJaJmHsHh荌h6CJH*PJaJh荌h66丆JaJh荌h6CJH*aJh荌h6CJaJjh荌CJUaJ!j擥h荌h荌CJEHUaJjL槄_ h荌CJUVaJh荌CJaJ$ ">@BDdjlp&,.2BDhjxzLV疱鹫疱瞥棋уу瞥棋瞥棋涘涘涘涘涘瞥棋涘涘愬涘h荌h6CJaJmHsHh荌h荌CJaJh荌h6CJH*aJh荌h6CJH*aJ%h荌h6B*CJaJmHph3fsHh荌h6CJaJmHsHh荌h6CJaJmHnHuh荌h6CJaJjh荌h6CJUaJ-D r Y@YDYFY箬骟梵梵凼桨〗钂jj抂H[jj%h荌h6B*CJaJmHph3fsHh荌h6CJaJmHsH(h荌h6B*CJH*aJmHphsH%h荌h6B*CJaJmHphsHh荌h6B*CJaJphh荌hf眡'` B. 燫韕秐瞞\ONa2CO34l銐 z瀀'Y C. Na2CO3剉N4l銐詋孨4l銐 z'Y D. Na2CO34l銐秐瞞>f眡'` /f郪:NNaOH/f:_眡 24. 術N蚐擽 蚐擽irSm1u1.0 molL-1M栿0.5 molL-1(u20 min 1u0.6 molL-1M栿0.3 molL-1(u剉鰁魰/f( ) A. 20 min B. 40 min C. 10 min D. 60 min 25. 9hnc蚐擽`$ I2+SO2+2H2O=H2SO4+2HI a$ 2FeCl3+2HI=2FeCl2+I2+2HCl b$ 2FeCl2+Cl2=2FeCl3 颯鍂I-0Fe2+0Cl-0SO2剉貜烻'`1u:_0R1_剉z槒^/f( ) A. I->Fe2+>Cl->SO2 B. Cl->Fe2+>SO2>I- C. Fe2+>I->Cl->SO2 D. SO2>I->Fe2+>Cl- 孨0kXzz槝 (qQ9槝 蟢zz1R qQ 22R) 1. MnO4 粂P[(W N T薔(-N珗貜烻@b梍剉ir/f:_眡'`薔(-N______ -N'`薔(-N______ x'`薔(-N______0 2. 甠聣抾P[袕≧剉qQ'`/f______孴______0 3. 術粂P[gYB\5uP[抍^:N3s23p6 鍌鍕粂P[:N+1鱊粂P[ R:N______ 鍌:N-1鱊粂P[ R:N______0kXCQ }&{鱏 4. 騗鍂5u鵞Fe3+/Fe2+, Fe2+/Fe, MnO4-/Mn2+, Sn4+/Sn2+, I2/I-, Cl2/Cl- ((V): 0.77 -0.41 1.491 ((V): 0.77 -0.41 1.491 0.15 0.54 1.36 N饛ir(-N g:_剉貜烻BR/f______ g:_剉'lSBR/f______ 齹\Fe3+貜烻bFe2+剉ir( g______0______0______0 5. 騗鍂AgCl剉Ksp=1.77(10-10 Ag2CrO4剉Ksp=1.12(10-12 HN颯秐'`剉詋儚 AgCl______Ag2CrO4kX(0(b= 0 6. S_GS貧)n鰁 鵞;mS齹'Y剉蚐擽 悋s瀀'Y剉 Ppe______kX'Y0\ 0 7. 褢R體-NC(C魰錘______BgSh廠慀v扤b. zz魰刧媁:N______0 體╔-NC(C魰錘______BgSh廠慀v扤b. .曇:N______0 8. 'lS'`HClO3 HClO x'`HClO3 HClOkX'Y嶯0\嶯bI{嶯 0 9. 騗鍂[Co(NH3)6]ClxHT梑義'` [Co(NH3)6]ClyHTz樍x'` Rx = _____ y =_____0 N0/f^棙$R璭 NR賁饛/f&Tcknx cknx剉(W靊鱏-N;u" 曪媱v;u qQ10\槝 蟢\槝1R qQ10R 1. 1u嶯菑 z剉韕He擽NwQSO剉悇_ gsQ @b錘N*N蚐擽I{)nI{婼 N剉蚐擽韕N蚐擽wQSO/fR郠ek蹚L gsQ0( )答 2. C-C.晞v.朂:N348 kJmol-1 @b錘C=C蘏.晞v.朂:N2(348 kJmol-1 0( ) 3. 鵞HAc-NaAc睶秐瞞 燫eQ\蠎剉xb眡0bz蕬鰁 vQpHKa20( ) 8. 鰱蚐擽剉yr筽/f僛剉蚐擽悋sN蚐擽ir剉Sm鄀sQ0( ) 諎褃顅nfSf[ qQ4u ,{3u 9. -N胈粂P[剉M慚Ope(Wpe

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